The Thermal Decomposition of Ammonium Perchlorate Doped with Cu+2and Mn+2

Autor:	I. Pelly
Rok vydání:	1975
Předmět:	Electron transfer chemistry.chemical_compound Chemistry Thermal decomposition Inorganic chemistry Doping General Chemistry Ammonium perchlorate Decomposition Ion Catalysis
Zdroj:	Israel Journal of Chemistry. 13:171-180
ISSN:	0021-2148
DOI:	10.1002/ijch.197500025
Popis:	The thermal decomposition of ammonium perchlorate doped with Cu+2 and Mn+2 was studied, using DTA and TGA. Small concentrations (0.1 − 0.01%) of these ions inhibit the decomposition by eliminating the first exotherm. At higher concentrations a catalyzed decomposition is observed. Either the influence of doping ions on the mechanism of the thermal decomposition is different from that of added oxides or a modification of the electron transfer mechanism is needed.
Databáze:	OpenAIRE
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