Dicationic State of Dithiadiazafulvalene within a TCNQ Charge-Transfer Complex: Generation and Characterization

Autor:	N. Bellec, D. Lorcy, L. Piekara-Sady,§ and, R. Carlier, W. Pukacki, Albert Robert, A. Tallec, M. Trybuła, Sz. Los, Kamal Boubekeur
Rok vydání:	1999
Předmět:	chemistry.chemical_classification Nitrile General Chemical Engineering Inorganic chemistry Salt (chemistry) General Chemistry Crystal structure Electrochemistry Photochemistry Charge-transfer complex Redox Magnetic susceptibility chemistry.chemical_compound chemistry Materials Chemistry Molecule
Zdroj:	Chemistry of Materials. 11:3147-3153
ISSN:	1520-5002 0897-4756
DOI:	10.1021/cm990233t
Popis:	Dithiadiazafulvalenes (DTDAF) can be formed either chemically or electrochemically. Electrochemical investigations have been carried out on 2-ethylthio-1,3-thiazolium salts to determine the redox behavior of dithiadiazafulvalenes formed by cathodic coupling. Using an in situ method, the donor has been trapped in the medium and a crystalline charge-transfer salt with TCNQ has been isolated. The crystal structure and magnetic susceptibility data of this 1:3 complex established that the DTADF is in the dicationic state.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e36697a334f23528da8bf7f3fa6685cf https://doi.org/10.1021/cm990233t Zobrazit plný text záznamu