Condensation of o-thiocyanatoacetophenone with hydroxylamine. Properties and X-ray crystal structure analysis of (Z)-2-hydroxyimino4-methyl-2H-1,3-benzo[e]thiazine

Autor:	Enrico Gaetani, Mario Nardelli, Giancarlo Pelizzi, Tullo Vitali, Ferdinando Ronchini
Rok vydání:	1977
Předmět:	Crystallography chemistry.chemical_compound Hydroxylamine chemistry Thiazine Condensation X-ray Mass spectrum Structural formula Orthorhombic crystal system Crystal structure
Zdroj:	Journal of the Chemical Society, Perkin Transactions 2. :1114
ISSN:	1364-5471 0300-9580
DOI:	10.1039/p29770001114
Popis:	The i.r., u.v., n.m.r., and mass spectra, and X-ray crystal structure analysis of the title compound are given. Crystals are orthorhombic, with a= 14.100(6), b= 12.461(7), c= 4.972(2)A, space group P212121, Z= 4. The structure was solved by the heavy-atom technique and refined by least-squares to R 0.051. The structural formula of the compound, assigned on the basis of the X-ray analysis, is helpful in devising syntheses of 3-substituted 1,2-benzisothiazoles
Databáze:	OpenAIRE
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