Asymmetric Michael reaction. Deracemization of enolate by chiral crown ether

Autor:	László Tőke, Melinda Albert, László Fenichel
Rok vydání:	1995
Předmět:	chemistry.chemical_classification chemistry.chemical_compound Chemistry Methyl phenylacetate Organic Chemistry Drug Discovery Enantioselective synthesis Michael reaction Organic chemistry Methyl acrylate Biochemistry Crown ether
Zdroj:	Tetrahedron Letters. 36:5951-5954
ISSN:	0040-4039
DOI:	10.1016/0040-4039(95)01150-g
Popis:	Crown ethers anellated to sugar units have been used to catalyse the enantioselective carbon-carbon bond forming reaction of methyl phenylacetate with methyl acrylate. A novel CH-acid deracemization has also been discovered in this study.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e33abac03aa686b44c735e5600cbcbc2 https://doi.org/10.1016/0040-4039(95)01150-g Zobrazit plný text záznamu Full Text from ScienceDirect