The effects of Sm2O3 doping on properties of PNN–PZT ceramics near morphotropic phase boundary
Autor: | Hao Zhang, Cheng Cheng, Shun-Min Hu, De-Yi Zheng, Gui-Gui Peng, Jing Zhang |
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Rok vydání: | 2016 |
Předmět: |
Phase boundary
Materials science Niobium Analytical chemistry chemistry.chemical_element Nanotechnology 02 engineering and technology Lead zirconate titanate 01 natural sciences chemistry.chemical_compound 0103 physical sciences Ceramic Electrical and Electronic Engineering 010302 applied physics Ternary numeral system Doping 021001 nanoscience & nanotechnology Condensed Matter Physics Piezoelectricity Atomic and Molecular Physics and Optics Electronic Optical and Magnetic Materials Nickel chemistry visual_art visual_art.visual_art_medium 0210 nano-technology |
Zdroj: | Journal of Materials Science: Materials in Electronics. 28:1624-1630 |
ISSN: | 1573-482X 0957-4522 |
DOI: | 10.1007/s10854-016-5704-x |
Popis: | The present study is an investigation of the effects of Sm2O3 doping on properties near morphotropic phase boundary (MPB) of nickel niobium ternary system lead zirconate titanate (PNN–PZT) ceramics. Pb(Ni1/3Nb2/3)0.5 (Zr0.3Ti0.7)0.5O3 (0.5PNN–0.5PZT + xSm) piezoelectric ceramics were prepared by a traditional two-step solid-state reaction method. The specimens exhibit the homogeneous perovskite structure without the secondary phase. When x = 0.6 wt% and x = 0.8 wt%, their diffraction peaks are the most obvious, they may have the best P–T MPB composition. The samples exhibit the P–T MPB composition have a good properties, which is in accord with the electric properties variation and the crystalline grain variation well. When x = 0.6 wt%, the ceramics exhibited electric properties: d33 = 688 pC/N, kp = 0.579, er = 6260, tanδ = 0.0207. It shows that the P–T MPB composition have relationships with the electric properties variation and the crystalline grain variation to some extent. |
Databáze: | OpenAIRE |
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