A kinetic model of the dimerization of α-methylstyrene in the presence of high-silica zeolite Y
| Autor: | A. V. Balaev, Usein M. Dzhemilev, A. N. Khazipova, N. F. Grigor’eva, B. I. Kutepov |
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| Rok vydání: | 2012 |
| Předmět: |
Kinetic model
Chemistry General Chemical Engineering Kinetics Energy Engineering and Power Technology General Chemistry Kinetic energy High silica chemistry.chemical_compound Fuel Technology Adsorption Monomer Geochemistry and Petrology Computational chemistry Organic chemistry Mass action law Zeolite |
| Zdroj: | Petroleum Chemistry. 52:426-431 |
| ISSN: | 1555-6239 0965-5441 |
| DOI: | 10.1134/s0965544112060047 |
| Popis: | The kinetics of the dimerization of α-methylstyrene in the presence of high-silica zeolite HNaY has been studied, and a nine-stage scheme of the monomer conversion has been developed. Analysis of the kinetic models developed in the form of the Langmuir-Hinshelwood relationships and in terms of the mass action law has shown that the first model more adequately describes the experimental data. The numerical values of kinetic and adsorption parameters are represented. |
| Databáze: | OpenAIRE |
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