Characterization studies of a semi‐automated separation method for analysis ofnon‐orthosubstituted polychlorinated biphenyl (PCB) congeners in environmental samples
| Autor: | John P. Giesy, Lisa L. Williams |
|---|---|
| Rok vydání: | 1995 |
| Předmět: |
Chromatography
organic chemicals Health Toxicology and Mutagenesis food and beverages Polychlorinated biphenyl Fractionation Pollution chemistry.chemical_compound chemistry Environmental chemistry embryonic structures bacteria Environmental Chemistry Graphitic carbon Separation method heterocyclic compounds Automated method |
| Zdroj: | Toxicological & Environmental Chemistry. 51:229-241 |
| ISSN: | 1029-0486 0277-2248 |
| Popis: | Non‐ortho substituted polychlorinated biphenyl (PCB) congeners can account for the majority of the dioxin‐like toxicity in environmental samples, yet analysis for these congeners is difficult because other PCB congeners co‐elute with them in most Chromatographic methods. An automated method was developed which incorporates a porous graphitic carbon (PGC) column which is commercially available. Non‐ortho substituted congeners were successfully separated from interfering PCB congeners. Recoveries of non‐ortho substituted congeners were consistently reproducible (CV < 9%) when chicken eggs were fortified with individual congeners. |
| Databáze: | OpenAIRE |
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