Processing and microstructure of a fluorite high-entropy oxide (Zr0.2Ce0.2Hf0.2Y0.2Al0.2)O2-δ
| Autor: | Yufu Liu, Yubin Wen |
|---|---|
| Rok vydání: | 2022 |
| Předmět: |
Quenching
Materials science Process Chemistry and Technology Configuration entropy Oxide Analytical chemistry Atmospheric temperature range Microstructure Fluorite Surfaces Coatings and Films Electronic Optical and Magnetic Materials law.invention chemistry.chemical_compound chemistry law Materials Chemistry Ceramics and Composites Calcination Grain boundary |
| Zdroj: | Ceramics International. 48:2546-2554 |
| ISSN: | 0272-8842 |
| DOI: | 10.1016/j.ceramint.2021.10.037 |
| Popis: | Typical high-entropy fluorite oxides with five metal cations have exhibited improved thermomechanical properties. In this work, we have successfully prepared single-phase high-entropy (Zr0.2Ce0.2Hf0.2Y0.2Al0.2)O2-δ fluorite oxides through the combination of sol-gel method and calcination, using metal nitrate/chloride, citric acid and absolute ethanol as the primary raw materials. A series of characterizations were employed for chemical, morphological and structural analysis of the calcined products. The five cationic elements were shown to be uniformly distributed in the nearly pure fluorite oxide without apparent segregation at the micro/nano-meter scales after 1500 °C calcination. Annealing and water quenching within the test temperature range did not witness any appreciable phase transition. It is revealed that the concentration of Ce3+ in Ce ions reaches 33.84% and δ is equal to 0.234, yielding a nominal composition of (Zr0.2Ce0.2Hf0.2Y0.2Al0.2)O1.766. Cation and anion configurational entropy were found to be 1.609 R and 0.722 R, respectively, where R is the ideal gas constant, for a sum of the total configurational entropy of 2.331 R in the high-entropy system. Line defects inside the crystals and 3 types of crystalline boundary structures have been observed and identified among the mostly atomically sharp grain boundaries. |
| Databáze: | OpenAIRE |
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