A Mass Spectrometric Study of Copper Bis(Acetylacetonate) with Allowance for the Isotopic Composition of the Metals
| Autor: | Yu. M. Metelsky, M. S. Kazak, N. N. Kostyuk, T. A. Dik |
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| Rok vydání: | 2019 |
| Předmět: |
Materials science
Solid-state physics Analytical chemistry chemistry.chemical_element Allowance (engineering) 010402 general chemistry 010403 inorganic & nuclear chemistry Mass spectrometry 01 natural sciences Copper Isotopic composition 0104 chemical sciences Inorganic Chemistry Metal chemistry visual_art Materials Chemistry visual_art.visual_art_medium Mass spectrum Physical and Theoretical Chemistry Intensity (heat transfer) |
| Zdroj: | Journal of Structural Chemistry. 60:1940-1945 |
| ISSN: | 1573-8779 0022-4766 |
| DOI: | 10.1134/s0022476619120096 |
| Popis: | Copper bis(acetylacetonate) is studied using mass spectrometry taking account of the natural isotopic composition of the metal. Valid data are obtained for the intensity of copper cations in the mass spectrum, which are confirmed by expected intensity ratios of copper-containing signals in the form of doublets. A new scheme for the main directions of Cu(acac)2 destruction is proposed. The assignment of cation signals in the mass spectrum is performed with a special software by representing Cu(acac)2 as a special discrete structure, a labeled simple graph G. |
| Databáze: | OpenAIRE |
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