Kinetics of Isothermal Pyrolysis of Iodomethanes in the Gas Phase

Autor:	A. G. Rebrova, G. A. Skorobogatov, V. K. Khripun
Rok vydání:	2005
Předmět:	chemistry.chemical_compound Reaction rate constant chemistry Kinetics Physical chemistry Diiodomethane General Chemistry Limiting Pyrolysis Isothermal process Gas phase
Zdroj:	Russian Journal of General Chemistry. 75:1524-1536
ISSN:	1608-3350 1070-3632
DOI:	10.1007/s11176-005-0462-0
Popis:	The limiting step of the isothermal pyrolysis of gaseous iodomethane (CH3I → 3/4CH4 + 1/2I2 + 1/(4n)C n ) and diiodomethane (CH2I2 → 1/2CH4 + I2 + 1/(2n)C n ) are the reactions 2CHI → C2 + 2HI and 2CI2 → C2 + 2I2, respectively. The rate constants of these reactions were determined.
Databáze:	OpenAIRE
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