Copper(I) Complexes of Bithiazoles
| Autor: | Kirsten Krause, Ronald A. Krause, Susan Lamtruong |
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| Rok vydání: | 1988 |
| Předmět: | |
| Zdroj: | Journal of Coordination Chemistry. 19:91-99 |
| ISSN: | 1029-0389 0095-8972 |
| DOI: | 10.1080/00958972.1988.9728147 |
| Popis: | Several new copper(I) complexes of a group of bidentate bithiazole ligands have been isolated. The compounds prepared are bis(2,2′-dimethyl-4,4′-bithiazole)copper(I) perchlorate ([Cu(me-b)2]ClO4), bis(4,4′-dimethyl-2,2′-bithiazole)copper(I) perchlorate ([Cu(me-i)2]ClO4), bis(2,2′-diphenyl-4,4′-bithiazole) copper(I) perchlorate ([Cu(ph-b)2]ClO4), bis(4,4′-diphenyl-2,2′-bithiazole)copper(I) perchlorate ([Cu(ph-i)2]ClO4), bis(4,4′,5,5′-tetraphenyl-2,2′-bithiazole)-copper(I) perchlorate ([Cu(ph4-i)2]ClO4, bis(2,2′-bithiazole)copper(l) perchlorate ([Cu(i)2]CIO4), 2,2′-bithiazolecopper(I) perchlorate ([Cu(i)ClO4), (2,2′-bithiazole)bis(triphenylphosphinesulfide)copper(I) perchlorate ([Cu(i)(SPph3)2]ClO4,(2,2′-bithiazole)bis-( triphenylphosphine)copper(I) perchlorate ([Cu(i)(Pph3)2]ClO4), and (4,4′-bithiazole)bis(triphenylphosphine) copper(I) perchlorate ([Cu(b)(Pph3)2]ClO4). Several synthetic techniques were required including one developed in this work which involved the conversion of [Cu(Pph3)4]ClO4 into the t... |
| Databáze: | OpenAIRE |
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