Analysis of the intensity and phase delay of photoinduced infrared absorption from poly(2,5-thienylenevinylene)

Autor:	Yukio Furukawa, Yun Hwan Cha, Takanobu Noguchi, Mitsuo Tasumi, Toshihiro Ohnishi
Rok vydání:	1997
Předmět:	Nonlinear system Chemistry Modulation Kinetics Analytical chemistry General Physics and Astronomy Infrared spectroscopy Physical and Theoretical Chemistry Polaron Molecular physics Spectral line Intensity (physics) Group delay and phase delay
Zdroj:	Chemical Physics Letters. 280:464-468
ISSN:	0009-2614
DOI:	10.1016/s0009-2614(97)01174-3
Popis:	Photoinduced infrared absorption spectra have been measured from poly(2,5-thienylenevinylene) by the phase-modulation method with modulation frequencies between 0.8 and 15 kHz. The modulation-frequency dependencies of the intensity and phase delay of the photoinduced infrared absorption have been numerically simulated by the use of a model based on second-order kinetics involving a neutralization recombination process between the positive and negative polarons. This numerical method is useful in analysing the nonlinear response associated with a bimolecular process.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e276a6a725d725a3cc416c0a41a812d6 https://doi.org/10.1016/s0009-2614(97)01174-3 Zobrazit plný text záznamu Full Text from ScienceDirect