Identification of Barrenwort flavonoids by high-resolution tandem mass spectrometry
| Autor: | V. M. Goncharov, A. M. Antokhin, Oleg A. Shpigun, V. F. Taranchenko, Igor Rodin, D. A. Mitrofanov, A. A. Ikhalainen, A. V. Aksenov, K. Yu. Vasil’ev, O. A. Shevlyakova |
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| Rok vydání: | 2016 |
| Předmět: |
Chromatography
010405 organic chemistry Chemistry 010401 analytical chemistry Analytical chemistry food and beverages High resolution Carbon-13 NMR Tandem mass spectrometry Mass spectrometry 01 natural sciences Dissociation (chemistry) 0104 chemical sciences Analytical Chemistry Ion Fragmentation (mass spectrometry) Mass spectrum |
| Zdroj: | Journal of Analytical Chemistry. 71:768-776 |
| ISSN: | 1608-3199 1061-9348 |
| DOI: | 10.1134/s106193481608013x |
| Popis: | Fragmentation of the main Barrenwort flavonoids—icariin, icaritin, icarisides I and II, and epimedins A and B—is studied by tandem mass spectrometry. High-resolution mass spectra of positively charged ions of these compounds are obtained under the conditions of collision-induced dissociation. Characteristic fragment ions are determined, which ensured the classification of unknown compounds as Barrenwort flavonoids. Epimedin C was isolated from raw plant material by preparative liquid chromatography; its structure was confirmed by 1H and 13C NMR spectra. |
| Databáze: | OpenAIRE |
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