Syntheses and magnetic properties of hexanuclear [Cp2Mn3(L1)4]2and octanuclear [Mn8(L2)12(μ4-O)2] (L1= 2-HNC5H5N, L2= 2-NH-3-Br-5-MeC5H3N, Cp = C5H5)

Autor:	Dominic S. Wright, Andrew D. Bond, Jeremy M. Rawson, Paul T. Wood, Mary McPartlin, Marta E. G. Mosquera, Richard A. Layfield, Carmen Soria Alvarez, Dale Cave, Eilis A. Harron
Rok vydání:	2002
Předmět:	chemistry.chemical_compound Magnetic measurements Crystallography Manganocene chemistry Materials Chemistry Metals and Alloys Ceramics and Composites General Chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials Metal clusters
Zdroj:	Chem. Commun.. :2980-2981
ISSN:	1364-548X 1359-7345
DOI:	10.1039/b209496g
Popis:	The reactions of manganocene, Cp2Mn, with 2-aminopyridine (L1H) or 2-amino-3-bromo-5-methylpyridine (L2H) give the novel hexanuclear and octanuclear Mn(II) amido cage compounds [Cp2Mn3(L1)4]2 (1) and [Mn8(L2)12(μ4-O)2] (2); magnetic measurements on which provide a rare insight into the magnetic properties of amido-bridged metal clusters.
Databáze:	OpenAIRE
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