Synthesis, crystal structure, and magnetic properties of an azido-bridged Mn(II) complex [C3H5NH3][Mn(N3)3]

Autor:	Jie Yang, Kun Qian, Zengtao Wang, Yiyong Xu
Rok vydání:	2017
Předmět:	chemistry.chemical_compound Crystallography 010405 organic chemistry Chemistry Coordination polymer Inorganic chemistry Antiferromagnetism General Chemistry Crystal structure 010402 general chemistry 01 natural sciences 0104 chemical sciences
Zdroj:	Zeitschrift für Naturforschung B. 72:409-413
ISSN:	1865-7117 0932-0776
DOI:	10.1515/znb-2016-0267
Popis:	A new compound [C3H5NH3][Mn(N3)3] has been synthesized, in which the Mn2+ ions are connected by the end-to-end azide anions to form the 3D architecture, while the C3H5NH3 + cations reside in the cavities of the Mn2+–N3 − network, forming rich N−H···N hydrogen bonds with the terminal N atoms of the azide anions. The complex has been characterized by IR spectroscopy, elemental analyses, and magnetic measurements. Magnetic susceptibility data indicate antiferromagnetic interaction among the MnII ions.
Databáze:	OpenAIRE
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