Solvent Extraction Behavior of Platinum(IV) and Palladium(II) as Chlorocomplex Acids with Trioctylphosphine Oxide

Autor:	Akihiko Okud, Isao Kobayashi, Yuko Hasegawa
Rok vydání:	1991
Předmět:	Chemistry Inorganic chemistry Extraction (chemistry) chemistry.chemical_element Chloride Analytical Chemistry Ion chemistry.chemical_compound Liquid–liquid extraction medicine Solvent extraction Platinum Trioctylphosphine oxide medicine.drug Palladium
Zdroj:	Analytical Sciences. 7:377-381
ISSN:	1348-2246 0910-6340
DOI:	10.2116/analsci.7.377
Popis:	In order to compare the extractions of platinum(IV) and palladium(II) complex acids with trioctylphosphine oxide (TOPO) to those of other inorganic acids, the distribution ratio of these metals between o-xylene containing TOPO and 4.0mol/dm3 (Na, H)(Cl, HSO4) has been measured at 298K. The extraction curves can be explained by the assumption that the dominant extracted species ratio of either platinum(IV) or palladium(II) would be 2:1:4 for proton:chlorocomplex anion:TOPO, at least in 4.0mol/dm3 chloride media. The extraction constants have been determined to be 105.01 for platinum(IV) and 104.04 for Palladium(II).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e26061bebb081d5dbca09bf36d0f6360 https://doi.org/10.2116/analsci.7.377 Zobrazit plný text záznamu Full text from SpringerLink