A New Dimeric Pd(III)Pd(II) Complex with 7,7,8,8 Tetracyanoquinodimethane (TCNQ)

Autor:	N. Mincheva, M. Mitewaa, Loreto Ballester, Liudmil Antonov
Rok vydání:	2000
Předmět:	Aqueous solution Chemistry Stereochemistry Ligand Tetracyanoquinodimethane law.invention Inorganic Chemistry chemistry.chemical_compound Crystallography Magnetochemistry law Basic solution Physical and Theoretical Chemistry Electron paramagnetic resonance Neutral molecule
Zdroj:	Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry. 30:1643-1651
ISSN:	1532-2440 0094-5714
DOI:	10.1080/00945710009351858
Popis:	A dimeric Pd(III)Pd(II) complex with TCNQ was prepared in an aqueous basic solution of pH∼9. This compound was characterized by elemental analyses and spectroscopic methods - IR. UV-Vis, EPR, magnetochemistry and ESCA. The results indicate that the formula of this complex is Pd2(TCNQ)3(OH)2, (TCNQ = 7,7,8,8-tetracyano-p-quinodimethane). The ligand TCNQ may exist in two different modes - as radical-anion TCNQ· and neutral molecule TCNQ.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e24bbfb20d4769254b374200db9f137c https://doi.org/10.1080/00945710009351858 Zobrazit plný text záznamu