Perturbation expansion for bond orders and the commutator [H, S]
Autor: | S. W. MacDowell, M. S. de Giambiagi, M. Giambiagi |
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Rok vydání: | 1965 |
Předmět: | |
Zdroj: | Il Nuovo Cimento. 35:410-418 |
ISSN: | 1827-6121 0029-6341 |
DOI: | 10.1007/bf02735327 |
Popis: | A perturbative expansion for Chirgwing and Coulson’s and Lowdin’s definitions of bond order is obtained, introducing explicitly the commutator [H, S]. Projection operator formalism is used in the development of the perturbation theory. Recurrence formulae are obtained for the corrections up to any order. The relation between both definitions is given. |
Databáze: | OpenAIRE |
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