Perturbation expansion for bond orders and the commutator [H, S]

Autor: S. W. MacDowell, M. S. de Giambiagi, M. Giambiagi
Rok vydání: 1965
Předmět:
Zdroj: Il Nuovo Cimento. 35:410-418
ISSN: 1827-6121
0029-6341
DOI: 10.1007/bf02735327
Popis: A perturbative expansion for Chirgwing and Coulson’s and Lowdin’s definitions of bond order is obtained, introducing explicitly the commutator [H, S]. Projection operator formalism is used in the development of the perturbation theory. Recurrence formulae are obtained for the corrections up to any order. The relation between both definitions is given.
Databáze: OpenAIRE