Simulation of electron ionization mass spectra of cycloalkyl fluorophosphonates

Autor:	A. O. Smirnov, Yu. I. Morozik, G. V. Galyaev
Rok vydání:	2011
Předmět:	chemistry.chemical_classification Homologous series chemistry.chemical_compound Hydrocarbon Fragmentation (mass spectrometry) Chemistry General chemistry Spectral image Mass spectrum Analytical chemistry Alkoxyl radicals General Chemistry Electron ionization
Zdroj:	Russian Journal of General Chemistry. 81:2088-2095
ISSN:	1608-3350 1070-3632
Popis:	The mass spectra of highly toxic cycloalkyl alkylfluorophosphonates can be divided into two components: organophosphorus and hydrocarbon. The organophosphorus component is a generalized spectral image of a taxonomic group among those forming a homologous series of cycloalkyl alkylfluorophosphonates. The hydrocarbon component is interpreted as a spectrum of the cycloolefin which is the main product of cycloalkyl alkylfluorophosphonate fragmentation. A method for simulation of the electron ionization mass spectra of these compounds is proposed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e22a68fbf9b2d5f72908458db3748250 https://doi.org/10.1134/s1070363211100082 Zobrazit plný text záznamu Plný text ve formátu PDF