ChemInform Abstract: Metal-Mediated Oxidation of Tertiary Alcohols and Related Fragmentations

Autor:	Jean Bernadou, Karine Wietzerbin, Bernard Meunier
Rok vydání:	2000
Předmět:	Metal Primary (chemistry) Fragmentation (mass spectrometry) Chemistry visual_art visual_art.visual_art_medium Organic chemistry General Medicine Tertiary alcohols Catalysis
Zdroj:	ChemInform. 31
ISSN:	1522-2667 0931-7597
DOI:	10.1002/chin.200050255
Popis:	In contrast to the abundant literature available on the oxidation of primary and secondary alcohols, examples of oxidation of tertiary alcohols are rather rare and a general review on this topic does not exist. Therefore, this microreview will briefly describe the different existing methods, mainly metal-mediated, which consist of one or two-electron oxidations and usually lead to rearrangement, cyclization or fragmentation products. Some related data is also given for fragmentation reactions observed in basic or acid medium, or catalyzed by metal complexes without a real oxidation step.
Databáze:	OpenAIRE
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