Insights in Reaction Mechanistics: Isotopic Exchange during the Metalation of Deuterated Tetraphenyl-21,23D-porphyrin on Cu(111)
| Autor: | Hans-Peter Steinrück, Mathias Laurin, Norbert Jux, Stefanie Ditze, Hubertus Marbach, Jörg Libuda, Matthias Franke, Michael Stark, Andre Kaftan, Ole Lytken, Quratulain Tariq, Michael Röckert, Dominik Lungerich |
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| Rok vydání: | 2014 |
| Předmět: |
Hydrogen
Metalation chemistry.chemical_element Photochemistry Porphyrin Spectral line Surfaces Coatings and Films Electronic Optical and Magnetic Materials Metal chemistry.chemical_compound General Energy chemistry Deuterium Desorption visual_art visual_art.visual_art_medium Dehydrogenation Physical and Theoretical Chemistry |
| Zdroj: | The Journal of Physical Chemistry C. 118:26729-26736 |
| ISSN: | 1932-7455 1932-7447 |
| Popis: | Through the use of temperature-programmed desorption (TPD), the self-metalation and dehydrogenation of deuterated 5,10,15,20-tetraphenyl-21,23D-porphyrin on Cu(111) have been studied, resulting in new insight into the metalation of porphyrins on surfaces. The metalation is found to proceed through the transfer of the central aminic hydrogen atoms to the Cu(111) surface and not, as suggested by gas phase calculations, through the combination of the hydrogen atoms to molecular hydrogen above the partially inserted metal center. This finding suggests that the metalation reaction could be significantly influenced by the stability of hydrogen on the substrate surface. The metalation reaction and the subsequent hydrogenation and dehydrogenation of the periphery of the porphyrin molecule leading to hydrogen–deuterium exchange are modeled with a simple microkinetic reaction model. The model is able to describe the main features of the TPD spectra. |
| Databáze: | OpenAIRE |
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