Quantum-chemical analysis of the nucleophilic substitution of the bromine atom by the cyano group at the sp-hybridized carbon atom in the methylbromoacetylene molecule
| Autor: | Alexander V. Vashchenko, Anastasiya G. Mal'kina, Vladimir I. Smirnov, Boris A. Trofimov, Yu. L. Frolov |
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| Rok vydání: | 2008 |
| Předmět: |
Substitution reaction
Cyanide chemistry.chemical_element Ring (chemistry) Photochemistry Copper Medicinal chemistry Inorganic Chemistry chemistry.chemical_compound chemistry Group (periodic table) Nucleophilic aromatic substitution Materials Chemistry Nucleophilic substitution Molecule Physical and Theoretical Chemistry |
| Zdroj: | Journal of Structural Chemistry. 49:395-398 |
| ISSN: | 1573-8779 0022-4766 |
| Popis: | This paper reports on our quantum-chemical analysis of the nucleophilic substitution of the bromine atom by the cyano group in the reaction of methylbromoacetylene with copper cyanide. According to calculations, the reaction can form a four-membered ring containing a copper atom. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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