Hebb–Wagner-type polarization/relaxation in the presence of the cross effect between electronic and ionic flows in a mixed conductor

Autor:	Han-Ill Yoo, Ki-Chun Lee
Rok vydání:	1999
Předmět:	Mixed conductor Cross effect Chemistry Analytical chemistry Thermodynamics Ionic bonding General Materials Science General Chemistry Boundary value problem Condensed Matter Physics Polarization (waves) Electrochemical potential Conductor
Zdroj:	Journal of Physics and Chemistry of Solids. 60:911-927
ISSN:	0022-3697
DOI:	10.1016/s0022-3697(99)00002-5
Popis:	Hebb–Wagner-type polarization and relaxation processes are theoretically analyzed in the presence of the cross effect between ionic and electronic flows in a mixed ionic/electronic conductor A 1− δ X. Analytic, transient solutions have been found for both processes in (i) potentiostatic ion-blocking, (ii) potentiostatic electron-blocking, (iii) galvanostatic ion-blocking, and (iv) galvanostatic electron-blocking conditions, respectively, when the perturbation of the system from equilibrium is not large. The salient features of the potentiostatic transients are discussed in comparison with the galvanostatic ones.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e1b917a9458089578e2e2bf238c4e029 https://doi.org/10.1016/s0022-3697(99)00002-5 Zobrazit plný text záznamu Full Text from ScienceDirect