A new family of silver(i) complexes stabilised by the phosphanylborane (C6H5)2PBH2·N(CH3)3

Autor:	Manfred Scheer, Oliver Hegen, Christian Marquardt, Michael Seidl, Mehdi Elsayed Moussa
Rok vydání:	2021
Předmět:	chemistry.chemical_classification chemistry.chemical_compound chemistry Coordination polymer Materials Chemistry General Chemistry Medicinal chemistry Catalysis Coordination complex
Zdroj:	New Journal of Chemistry. 45:14916-14919
ISSN:	1369-9261 1144-0546
Popis:	The reactions of the phosphanylborane Ph2PBH2·NMe3 (L) with Ag[FAl{OC6F10(C6F5)}3] (Ag[FAl]) and AgBF4 are studied. The first reaction allowed for the synthesis of the coordination compounds [Ag(Ph2P-BH2·NMe3)(CH3CN)][FAl] (1), [Ag(Ph2P-BH2·NMe3)2][FAl] (2) and [Ag(Ph2P-BH2·NMe3)3][FAl] (3), while the second reaction afforded the one-dimensional coordination polymer [Ag(Ph2P-BH2·NMe3)]n[BF4]n (4). Compounds 1–4 are the first reported Ag(I) complexes stabilised by phosphanylboranes.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e16adf9fca9785facf840441c1ee0209 https://doi.org/10.1039/d0nj01679a Zobrazit plný text záznamu