A new family of silver(i ) complexes stabilised by the phosphanylborane (C6H5)2PBH2·N(CH3)3
Autor: | Manfred Scheer, Oliver Hegen, Christian Marquardt, Michael Seidl, Mehdi Elsayed Moussa |
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Rok vydání: | 2021 |
Předmět: | |
Zdroj: | New Journal of Chemistry. 45:14916-14919 |
ISSN: | 1369-9261 1144-0546 |
Popis: | The reactions of the phosphanylborane Ph2PBH2·NMe3 (L) with Ag[FAl{OC6F10(C6F5)}3] (Ag[FAl]) and AgBF4 are studied. The first reaction allowed for the synthesis of the coordination compounds [Ag(Ph2P-BH2·NMe3)(CH3CN)][FAl] (1), [Ag(Ph2P-BH2·NMe3)2][FAl] (2) and [Ag(Ph2P-BH2·NMe3)3][FAl] (3), while the second reaction afforded the one-dimensional coordination polymer [Ag(Ph2P-BH2·NMe3)]n[BF4]n (4). Compounds 1–4 are the first reported Ag(I) complexes stabilised by phosphanylboranes. |
Databáze: | OpenAIRE |
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