Triarylphosphines : Molecular Geometry, Anodic Behavior and ESR Study of the Radical Cations

Autor:	G. Gronchi, F. Vila, Nouredine Redouane, Paul Tordo, Florence Chalier
Rok vydání:	1993
Předmět:	Chemistry Organic Chemistry X-ray Large series Electrochemistry Biochemistry law.invention Anode Inorganic Chemistry Bond length Molecular geometry Nuclear magnetic resonance law Physical chemistry Molecule Electron paramagnetic resonance
Zdroj:	Phosphorus, Sulfur, and Silicon and the Related Elements. 77:101-104
ISSN:	1563-5325 1042-6507
DOI:	10.1080/10426509308045629
Popis:	A large series of triarylphosphines has been prepared and their geometry was studied by force field calculations. A very good agreement was found between the calculated and experimental (X Ray) geometries. The oxidation potentials were determined by electrochemical techniques and the corresponding cations were studied by ESR. Both the oxidation potentials and the ESR features were shown to depend strongly on the molecular geometry.
Databáze:	OpenAIRE
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