Functionalization of Polymer Surfaces Using Excimer VUV Systems and Silent Discharges. Application to Electroless Metallization
| Autor: | M. Charbonnier, Hilmar Dr Esrom, Maurice Romand, R. Seeböck |
|---|---|
| Rok vydání: | 2001 |
| Předmět: |
chemistry.chemical_classification
Materials science Atmospheric pressure chemistry.chemical_element Sodium hypophosphite Surfaces and Interfaces General Chemistry Polymer Surfaces Coatings and Films chemistry.chemical_compound Xenon chemistry Chemical engineering Mechanics of Materials Materials Chemistry Surface modification Organic chemistry Metallizing Polyimide Palladium |
| Zdroj: | The Journal of Adhesion. 75:381-404 |
| ISSN: | 1545-5823 0021-8464 |
| Popis: | New approaches for electroless plating of nonconductive polymers or polymer-based materials are described. In this work, polyimide substrates were surface-functionalized (i) in nitrogenated (ammonia at reduced pressure) and oxygenated (air at atmospheric pressure) atmospheres under assistance of vacuum-ultraviolet (VUV) irradiation (use of a xenon silent discharge excimer source) or (ii) directly in air at atmospheric pressure using a dielectric-barrier discharge (DBD) device. After functionalization, the substrates were “activated” by dipping in a dilute acidic PdCl2 solution or by spin-coating of a thin metal-organic film (from a solution of palladium acetate (PdAc) in chloroform). The catalytic activity of the so-deposited palladium species toward the electroless deposition of nickel was studied before and after a VUV post-irradiation (in air at atmospheric or reduced pressure) with a view to understanding better the role of the reducer (sodium hypophosphite) within the electroless bath. This ... |
| Databáze: | OpenAIRE |
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