Stereoselective synthesis of (−)-tetrahydropyrenophorol
Autor: | Reddymasu Sreenivasulu, Bommareddy Pratapareddy, Vuppula Naresh Kumar, Mandava Venkata Basaveswara Rao, Rudraraju Ramesh Raju, Pradeepkumar Thota, Islavathu Hatti |
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Rok vydání: | 2016 |
Předmět: | |
Zdroj: | Monatshefte für Chemie - Chemical Monthly. 148:751-756 |
ISSN: | 1434-4475 0026-9247 |
DOI: | 10.1007/s00706-016-1754-2 |
Popis: | A simple and efficient synthesis of macrocyclic dilactone tetrahydropyrenophorol has been accomplished from inexpensive and commercially available starting materials. This concise synthesis utilizes regioselective ring opening of epoxide, asymmetric dihydroxylation, and Mitsunobu reaction for the construction of the macrolactone. |
Databáze: | OpenAIRE |
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