Resolution of inherently chiral anti-O,O′-dialkylthiacalix[4]arenes and determination of their absolute stereochemistries

Autor:	Takashi Kajiwara, Nariaki Sasagawa, Nobuji Matsumura, Koichi Natori, Tetsutaro Hattori, Fumitaka Narumi
Rok vydání:	2008
Předmět:	Inorganic Chemistry Crystallography Column chromatography Chemistry Organic Chemistry Resolution (electron density) Physical and Theoretical Chemistry Catalysis
Zdroj:	Tetrahedron: Asymmetry. 19:1470-1475
ISSN:	0957-4166
DOI:	10.1016/j.tetasy.2008.05.034
Popis:	Inherently chiral anti - O , O ′-dibenzyl- and anti - O , O ′-dibutyl- p - tert -butylthiacalix[4]arenes 4 and 6 are resolved as ( S )-2-methoxy-2-(naphthalen-1-yl)propionic esters by flash chromatography. The absolute stereochemistries were determined to be ( S a )-(+)- 4 and ( S a )-(+)- 6 by X-ray crystallographic analyses.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e12b4e2386e00d66fae781c7a9139358 https://doi.org/10.1016/j.tetasy.2008.05.034 Zobrazit plný text záznamu Full Text from ScienceDirect