Rearrangement of allylic sulfoximines to allylic sulfinamides

Autor:	Matthias Scommoda, H.‐J. Gais, Dirk Lenz
Rok vydání:	1994
Předmět:	Allylic rearrangement Chemistry Organic Chemistry Thermal decomposition Biochemistry law.invention chemistry.chemical_compound Sulfinamide law Drug Discovery Organic chemistry Walden inversion Pyrolysis Racemization
Zdroj:	Tetrahedron Letters. 35:7361-7364
ISSN:	0040-4039
DOI:	10.1016/0040-4039(94)85314-2
Popis:	Thermolysis of the enantiomerically pure allylic sulfoximines 3a,b leads to their partial rearrangement to the isomeric allylic sulfinamides 5a,b and 6a,b, respectively, with complete retention of configuration at the S-atom. Racemization of the allylic sulfoximines 3a,b at the S-atom does not occur.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e12916f21688eeca3ef556bc092ad8b8 https://doi.org/10.1016/0040-4039(94)85314-2 Zobrazit plný text záznamu