Exploring the Limits of Catalytic Ammonia–Borane Dehydrogenation Using a Bis(N-heterocyclic carbene) Iridium(III) Complex
| Autor: | Jonathan D. Egbert, David J. Nelson, Steven P. Nolan, Byron J. Truscott |
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| Rok vydání: | 2013 |
| Předmět: |
010405 organic chemistry
Organic Chemistry Ammonia borane chemistry.chemical_element 010402 general chemistry 01 natural sciences 3. Good health 0104 chemical sciences Catalysis Inorganic Chemistry chemistry.chemical_compound chemistry Organic chemistry Dehydrogenation Iridium Solvolysis Physical and Theoretical Chemistry Carbene |
| Zdroj: | Organometallics. 32:3769-3772 |
| ISSN: | 1520-6041 0276-7333 |
| DOI: | 10.1021/om400402r |
| Popis: | Ammonia borane dehydrogenation can be catalyzed by a number of organometallic species. [Ir(κ2-ItBu)2][PF6] (ItBu = 1,3-bis(tert-butyl)imidazol-2-ylidene) is the most active catalyst for this proces... |
| Databáze: | OpenAIRE |
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