| Autor: |
R. K. M. R. Kallury, John H. Bowie, P. F. Donaghue, B.K. Simons |
| Rok vydání: |
1969 |
| Předmět: |
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| Zdroj: |
Tetrahedron. 25:3969-3974 |
| ISSN: |
0040-4020 |
| DOI: |
10.1016/s0040-4020(01)82930-6 |
| Popis: |
The spectra of benzyl phenyl ketone derivatives contain ions at m/e 165 (C 13 H 9 ) which are produced by skeletal-rearrangement processes. The rearrangement peak is most pronounced in the spectrum of the oxime of benzyl phenyl ketone where it arises mainly from an M-H 2 O species. Deuterium labelling studies and metastable characteristics are consistent with the M - 18 species having the properties of a 2.3-diphenyl-2-H-azirine molecular ion. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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