Laser spectroscopy and upconversion studies of Pr3+-doped halide modified sulfide glasses
Autor: | A. Mendioroz, J.L. Adam, José A. Fernández, Rolindes Balda, M.A. Arriandiaga, Laurent Griscom |
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Rok vydání: | 2001 |
Předmět: |
chemistry.chemical_classification
Photoluminescence Sulfide Chemistry Organic Chemistry Far-infrared laser Doping Analytical chemistry Halide Atomic and Molecular Physics and Optics Photon upconversion Electronic Optical and Magnetic Materials Inorganic Chemistry Electrical and Electronic Engineering Physical and Theoretical Chemistry Luminescence Spectroscopy |
Zdroj: | Optical Materials. 16:249-254 |
ISSN: | 0925-3467 |
DOI: | 10.1016/s0925-3467(00)00085-9 |
Popis: | The visible luminescence of Pr 3+ -doped halide modified sulfide glasses has been investigated for different halide modifiers and Pr 3+ concentrations by using steady-state and time-resolved laser spectroscopy. The measured luminescence lifetime of level 3 P 0 is nearly independent on Pr 3+ concentration up to 0.7 mol% whereas the fluorescence of the 1 D 2 level shows concentration quenching for Pr 3+ concentrations higher than 0.5 mol% even at low temperature. The IR-to-visible upconversion obtained under continuous wave infrared laser excitation has been investigated for all samples. The excitation wavelength and pumping power dependencies of the upconverted emission allow to point out two different upconversion mechanisms to populate the 3 P 0 and 1 D 2 levels. |
Databáze: | OpenAIRE |
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