Single Crystals Synthesis and Refinement of the Crystal Structure of the Polymerized Tetragonal Phase of C60

Autor:	V. A. Davydov, L. S. Kashevarova, V. I. Kulakov, A. V. Dzyabchenko, A. V. Rakhmanina, B. Narymbetov, V. N. Agafonov
Rok vydání:	2005
Předmět:	Diffraction Fullerene Materials science Organic Chemistry Random combination Crystal structure Atomic and Molecular Physics and Optics Tetragonal crystal system Crystallography Polymerization Phase (matter) General Materials Science Physical and Theoretical Chemistry Single crystal
Zdroj:	Fullerenes, Nanotubes and Carbon Nanostructures. 12:275-279
ISSN:	1536-4046 1536-383X
DOI:	10.1081/fst-120027169
Popis:	The possibilities of single crystals synthesis in conditions of nonisotropic one‐axis contraction were studied. As a result of the work the single crystals of the tetragonal polymerized phase of C60 without orientational domains were obtained. The crystal structure of this phase was resolved using single crystal x‐ray diffraction data. A structural model of this phase proposed early was confirmed and refined to final R = 0.075. The structure is slightly disordered. It consists of a random combination of the P 4 2/mmc layers (84%) and of the Immm layers (16%), along the c axis.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e0ef3230ecbe70eb115fd5f95abe113c https://doi.org/10.1081/fst-120027169 Zobrazit plný text záznamu