V-Containing Heteropoly Acids with Keggin Structure as Precursors of Sulfide Catalysts: Regularities of the Convertion of Dibenzothiophene and Naphthalene on Nonpromoted Mo–V Catalysts

Autor:	V. V. Timoshkina, S. V. Yudintsev, E. D. Frenkel’, A. A. Pimerzin
Rok vydání:	2022
Předmět:	Fuel Technology Geochemistry and Petrology General Chemical Engineering Energy Engineering and Power Technology General Chemistry
Zdroj:	Petroleum Chemistry. 62:779-787
ISSN:	1555-6239 0965-5441
Popis:	Abstract Mixed PMoV heteropoly acids with Keggin structures H3+xPMo12–xVxO40 (x = 1–6) and modified sulfide catalysts on their basis were synthesized, their physicochemical characteristics were determined, and their performance in the reactions of hydrodesulfurization (HDS) of dibenzothiophene (DBT) and hydrogenation of naphthalene was evaluated. Modification of the Mo-containing catalysts with vanadium by impregnation with a solution of mixed heteropoly acids was found to enhance their catalytic activity in the studied reactions, as well as to increase the selectivity for the direct hydrodesulfurization route of the DBT HDS reaction.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e0e416f7f6032822ed2ba4333b87a60b https://doi.org/10.1134/s0965544122050085 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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