Synthesis of UiO-66-NH2 derived heterogeneous copper (II) catalyst and study of its application in the selective aerobic oxidation of alcohols

Autor:	Jia Tang, Mu Yang, Junying Hou, Yunfeng Lu, Allison M. Wensley, Yi Luan
Rok vydání:	2015
Předmět:	Chemistry Process Chemistry and Technology fungi Inorganic chemistry chemistry.chemical_element Heterogeneous catalysis Copper Oxygen Catalysis chemistry.chemical_compound Salicylaldehyde Alcohol oxidation Metal-organic framework Physical and Theoretical Chemistry Powder diffraction
Zdroj:	Journal of Molecular Catalysis A: Chemical. 407:53-59
ISSN:	1381-1169
Popis:	The three-dimensional Zr-based metal-organic framework UiO-66-NH2 was functionalized with salicylaldehyde using a post-synthetic modification (PSM) strategy, and then three kinds of copper (II) salts were successfully immobilized onto the surface of the amino-functionalized Zr-MOF. The SEM and PXRD results showed that the morphology and structure of Zr-MOF were retained after multiple transformations. The obtained UiO-66-Sal-CuCl2 catalyst exhibited excellent activity for the selective aerobic oxidation of primary aromatic alcohols using molecular oxygen as the oxygen source. Furthermore, the UiO-66-Sal-CuCl2 catalyst showed a good cycle performance.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e0db6b99c183f83c0b36f8115390d1c7 https://doi.org/10.1016/j.molcata.2015.06.018 Zobrazit plný text záznamu Full Text from ScienceDirect