Improved preparative electrochemical oxidation of d-glucose to d-glucaric acid

Autor:	Mathias Ibert, Patrick Fuertes, Nabyl Merbouh, Christian Feasson, Catherine Fiol-Petit, Francis Marsais
Rok vydání:	2010
Předmět:	Aldaric acid General Chemical Engineering Inorganic chemistry chemistry.chemical_element Electrochemistry Glucaric Acid Anode chemistry.chemical_compound chemistry Transition metal D-Glucose Cyclic voltammetry Platinum
Zdroj:	Electrochimica Acta. 55:3589-3594
ISSN:	0013-4686
DOI:	10.1016/j.electacta.2009.11.041
Popis:	The 2,2,6,6-tetramethyl-1-piperidinyloxy free radical (TEMPO) mediated electrochemical oxidation of d -glucose to d -glucaric acid on a synthetically useful scale is reported. Using TEMPO and a graphite felt anode combined with a stainless steel cathode, d -glucose was oxidized under different conditions (pH, temperature, co-oxidant), and the reaction outcomes were analyzed. Optimized conditions for such oxidation are provided along with few new interesting results unique to this reaction, such as the appearance of a novel triacid.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e0c2312940745a6dfa77e6e22163b74f https://doi.org/10.1016/j.electacta.2009.11.041 Zobrazit plný text záznamu Full Text from ScienceDirect