Thermodynamic studies on thin liquid films. V. General formulation for spherical films

Autor: Hidemi Iyota
Rok vydání: 2013
Předmět:
Zdroj: Colloid and Polymer Science. 291:2663-2679
ISSN: 1435-1536
0303-402X
DOI: 10.1007/s00396-013-2983-0
Popis: Thermodynamic equations were derived for adsorption at interfaces of spherical films and interaction between interfaces in a film. The dependence of film tension on capillary pressure between external and film-forming phases gave thermodynamic film thickness and the one on pressure difference across the film the distance between the surface of tension for the film and the innermost dividing surface. Curvature dependence of film tension was numerically evaluated by using one of the derived equations.
Databáze: OpenAIRE