| Autor: |
David Gray, Graham H. Cross, David Healy, David Bloor, Tony L. Axon, Michael Swann, Marek Szablewski, Maria Farsari |
| Rok vydání: |
1994 |
| Předmět: |
|
| Zdroj: |
SPIE Proceedings. |
| ISSN: |
0277-786X |
| DOI: |
10.1117/12.187541 |
| Popis: |
We report the synthesis and evaluation of new highly polar molecules whose combined non- linear and linear optical properties are of interest for frequency doubling. The generic scheme for the syntheses rests on enamine substitutions of tetracyano-p-quinodimethane (TCNQ). In the case detailed, a novel reaction product is reported from the unexpected reaction of triethylamine and TCNQ. In polar solvents such as DMF, the molecule has a charge separated ground state and a measured bipole moment of 45 D. Also in polar solvents, the value for the resonant (beta) coefficient is measured to be -190 X 10-30 esu. Coupled with acceptable transparency at 460 nm ((epsilon) equals 86 M-1 cm-1) this molecule points to a new approach in the design of such materials.© (1994) COPYRIGHT SPIE--The International Society for Optical Engineering. Downloading of the abstract is permitted for personal use only. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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