Di(adamant-1-yl)- and di(adamant-2-yl)thiophosphoric acids and their triethylammonium salts in alkylation reactions

Autor: A. G. Yurchenko, R. I. Yurchenko, Yu. M. Klimko, Ekaterina D. Butova, A. A. Esipenko
Rok vydání: 2009
Předmět:
Zdroj: Russian Journal of General Chemistry. 79:1632-1634
ISSN: 1608-3350
1070-3632
DOI: 10.1134/s1070363209080076
Popis: By reaction of di(adamant-1-yl) and di(adamant-2-yl) phosphites with sulfur in the presence of triethylamine diadamantylthiophosphoric acid triethylammonium salts were obtained. The latter by the action of hydrochloric acid were converted into free thiophosphoric acids and by the reaction of alkylation into the respective triesters which have thionic structure. Applicability in such reactions also of triethylammonium salts of diadamantyldithiophosphoric acids was demonstrated.
Databáze: OpenAIRE