The Reaction of Perfluorobutanesulfonyl Fluoride with Alcohols in the Presence of 4-Dialkylaminopyridines

Autor:	Helmut Vorbrüggen, Konrad Krolikiewicz, B. Bennua‐Skalmowski
Rok vydání:	2010
Předmět:	chemistry.chemical_compound Neopentyl alcohol Primary (chemistry) chemistry Nucleophile Organic chemistry General Chemistry Perfluorobutanesulfonyl fluoride
Zdroj:	Bulletin des Sociétés Chimiques Belges. 103:453-461
ISSN:	0037-9646
Popis:	Primary hydroxy groups as in neopentyl alcohol 7 or neopentylglycol 18 react readily with perfluorobutanesulfonyl fluoride 1 in the presence of 2 equiv. of the nucleophilic 4-dialkylaminopyridines 4 to afford high yields of the corresponding N-alkyl-4-dialkylaminopyridinium perfluorobutanesulfonates (nonaflates). Secondary hydroxy groups give rise to a mixture of the corresponding olefins and monofluorides as well as of the corresponding N-alkyl-4-dialkylaminopyridinium nonaflates.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e09132efa683b9102dac86c516b3170e https://doi.org/10.1002/bscb.19941030720 Zobrazit plný text záznamu