A New Nasicon-Type Phosphate:Co0.5Ti2(PO4)3II. Simulation of Optical and Magnetic Properties
| Autor: | L. Beaury, A. El Jazouli, J. Derouet, R. Olazcuaga, G. Le Flem, A.El Bouari, Pierre Porcher, J. M. Dance |
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| Rok vydání: | 1999 |
| Předmět: |
Field (physics)
Stereochemistry Chemistry Crystal structure Condensed Matter Physics Magnetic susceptibility Molecular physics Electronic Optical and Magnetic Materials Inorganic Chemistry Crystal Paramagnetism Crystal field theory Materials Chemistry Ceramics and Composites Fast ion conductor Crystallite Physical and Theoretical Chemistry |
| Zdroj: | Journal of Solid State Chemistry. 143:230-238 |
| ISSN: | 0022-4596 |
| DOI: | 10.1006/jssc.1998.8098 |
| Popis: | The optical (energy level scheme) and magnetic properties (paramagnetic susceptibility as a function of the temperature and g values) of the polycrystalline Co 0.5 Ti 2 (PO 4 ) 3 were simultaneously reproduced by use of a crystal field theory involving a set of F k , ζ , free ion, and B k q crystal field parameters. The crystal field parameters calculated from the structure are in fair agreement with the experimental ones and permit us to assign R 32 as the space group of the crystal structure. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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