Molecular weight dependence of healing and brittle fracture in amorphous polymers above the entanglement molecular weight

Autor:	Stephen Prager, Douglas Brian Adolf, Matthew Tirrell
Rok vydání:	1985
Předmět:	chemistry.chemical_classification Materials science Diffusion General Engineering Quantum entanglement Polymer Physics::Geophysics Amorphous solid Condensed Matter::Soft Condensed Matter Stress (mechanics) Reptation Brittleness chemistry Polymer chemistry Fracture (geology) Composite material
Zdroj:	Journal of Polymer Science: Polymer Physics Edition. 23:413-427
ISSN:	1542-9385 0098-1273
DOI:	10.1002/pol.1985.180230214
Popis:	A model based on chain entanglements is developed to predict the molecular weight dependence of the fracture stress for brittle, amorphous polymers. It is then used in conjunction with the reptation model of polymer diffusion to predict the time and molecular weight dependence of the fracture stress in the closely related healing problem. Theoretical predictions are found to be in close agreement with experimental data.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e0811a97cbe6b03907699f9fcede85f6 https://doi.org/10.1002/pol.1985.180230214 Zobrazit plný text záznamu Plný text