Impact dynamics of molecular clusters on surfaces: Fragmentation patterns and anisotropic effects
| Autor: | Hartmut Schröder, Christoph Gebhardt, Karl-Ludwig Kompa, Anna Tomsic |
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| Rok vydání: | 2003 |
| Předmět: | |
| Zdroj: | The Journal of Chemical Physics. 119:6314-6323 |
| ISSN: | 1089-7690 0021-9606 |
| DOI: | 10.1063/1.1603213 |
| Popis: | The fragmentation dynamics of (H2O)1032 clusters colliding with a repulsive surface at incident velocities of 1753 m/s and 2909 m/s, corresponding to kinetic energies of 0.5 and 1.5 times the cluster binding energy, has been examined in a classical molecular dynamics simulations study. The results show a large anisotropy in the energy redistribution inside the cluster upon impact, which leads to asymmetric fragmentation, starting in the leading part of the cluster. The low-mass region of the fragment size distribution can be described by a power law with an exponent close to −1.6, and the range of this region increases with increasing incident velocity. The formed fragments have rather uniform internal temperatures close to the standard boiling point of water, but the translational energy of the monomers formed upon collision is much larger, pointing at the asymmetric energy distribution inside the cluster. The angular distributions of fragment mass and fragment kinetic energy peak at grazing exit angles.... |
| Databáze: | OpenAIRE |
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