Kinetics of the decomposition of ?-hydroxyethylperacetate catalyzed by cobalt acetate

Autor:	Maxim G. Vinogradov, B. S. Strel'chik, G. I. Nikishin, M. L. Gringol'ts
Rok vydání:	1984
Předmět:	Coordination sphere Chemistry Thermal decomposition chemistry.chemical_element General Chemistry Photochemistry Decomposition Peroxide Homolysis Catalysis chemistry.chemical_compound Acetic acid Polymer chemistry Cobalt
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 33:1351-1355
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00956504
Popis:	1. The mechanism of the reaction, consisting of homolytic decomposition of two molecules of peroxide in the coordination sphere of Co(III), was proposed based on the study of the kinetics of decomposition of α-hydroxethylperacetate catalyzed by cobalt acetate in a solution of acetaldehyde. 2. In the thermal decomposition of α-hydroxyethylperacetate, a homolytic reaction of decomposition of the peroxide with liberation of CH4, and CO2 takes place in addition to the monomolecular heterolytic reaction of formation of acetic acid.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e061f188a9a7ef909b7d6557c2956dc3 https://doi.org/10.1007/bf00956504 Zobrazit plný text záznamu Full text from SpringerLink