η3-Propargyl complexes of molybdenum, tungsten, and rhenium

Autor:	E. S. Taits, Pavel V. Petrovskii, V. V. Krivykh
Rok vydání:	1999
Předmět:	Ligand Inorganic chemistry chemistry.chemical_element Infrared spectroscopy General Chemistry Propargyl alcohol Rhenium Tungsten Medicinal chemistry chemistry.chemical_compound chemistry Molybdenum Propargyl Irradiation
Zdroj:	Russian Chemical Bulletin. 48:1774-1781
ISSN:	1573-9171 1066-5285
Popis:	The reactions of the Me n C6H6−n M(CO)3 (M=Cr, Mo, W;n=3, 5, 6) and C5R5M(CO)3 (M=Mn, Re; R=H, Me) complexes with propargyl alcohol in acidic media under UV irradiation were studied. Novel Me n C6H6−n M(CO)2(η3-C3H3)BF4 (M=Mo, W;n=3, 5, 6) and C5R5Re(CO)2(η3-C3H3)CF3SO3 complexes with the 3ē-propargyl ligand were synthesized, and their properties compared with those of similar η3-allyl derivatives. The structure and dynamic propeties of the compounds obtained are discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e06042e91ed417fe062f17b337fc1804 https://doi.org/10.1007/bf02494828 Zobrazit plný text záznamu Full text from SpringerLink