Further evidence for the FeII-FeIV and FeIII-FeV manifolds in the substitution of saturated hydrocarbons

Autor:	Roy U. Rojas Wahl, Valérie N. Le Gloahec, Bin Hu, Nathalie C. Delanghe, Derek H. R. Barton, Béatrice M. Chabot
Rok vydání:	1995
Předmět:	Thiocyanate Radical Organic Chemistry Substitution (logic) Photochemistry Biochemistry Chloride Ion chemistry.chemical_compound chemistry Drug Discovery medicine Azide Nitrite medicine.drug
Zdroj:	Tetrahedron Letters. 36:7007-7010
ISSN:	0040-4039
DOI:	10.1016/0040-4039(95)01450-v
Popis:	The substitution of saturated hydrocarbons by the anions nitrite, thiocyanate, azide and chloride, using H2O2 and TBHP as oxidants has been shown to depend upon the FeII-FeIV manifold and to involve radical chemistry. As soon as the FeII has been oxidised to FeIII, the reactions proceed in the FeIII-FeV manifold where oxidation, but no anion substitution, is seen.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e04900a7ab70e0546bdf74c89bbe695d https://doi.org/10.1016/0040-4039(95)01450-v Zobrazit plný text záznamu Full Text from ScienceDirect