ChemInform Abstract: Photochemical Selective Fluorination of Organic Molecules Using Mercury(II) Fluoride

Autor: M. H. Habibi, Thomas E. Mallouk
Rok vydání: 2010
Předmět:
Zdroj: ChemInform. 22
ISSN: 0931-7597
DOI: 10.1002/chin.199152110
Popis: Organic compounds, such as triphenylacetic acid, triphenyl ethylene, and triethyl phosphite can be selectively fluorinated in dimethylsulfoxide/ HgF 2 solutions under UV-visible illumination. Product yields, determined by 19 F-NMR, are essentially quantitative for the compounds studied, and in some cases only a single fluorinated product is formed.
Databáze: OpenAIRE