ChemInform Abstract: Photochemical Selective Fluorination of Organic Molecules Using Mercury(II) Fluoride
Autor: | M. H. Habibi, Thomas E. Mallouk |
---|---|
Rok vydání: | 2010 |
Předmět: | |
Zdroj: | ChemInform. 22 |
ISSN: | 0931-7597 |
DOI: | 10.1002/chin.199152110 |
Popis: | Organic compounds, such as triphenylacetic acid, triphenyl ethylene, and triethyl phosphite can be selectively fluorinated in dimethylsulfoxide/ HgF 2 solutions under UV-visible illumination. Product yields, determined by 19 F-NMR, are essentially quantitative for the compounds studied, and in some cases only a single fluorinated product is formed. |
Databáze: | OpenAIRE |
Externí odkaz: |