Stereoselective synthesis of α-d-fructofuranosides using a 4,6-O-siloxane-protected donor

Autor: Xue Li, Yong Qin, Yao Huang, Xiao-Yu Liu, Rui Wang, Yanmei Wu, Jin-Song Yang, Huan He
Rok vydání: 2021
Předmět:
Zdroj: Organic Chemistry Frontiers. 8:2263-2267
ISSN: 2052-4129
Popis: A stereoselective glycosylation approach to α-D-fructofuranosides employing a 4,6-O-tetraisopropyldisiloxanylidene-containing thio-fructofuranoside donor is described. This method features broad substrate scope and good functional-group tolerance, which allowed the efficient synthesis of the α-isomers of inulin oligosaccharides.
Databáze: OpenAIRE