Solvent and additive-free selective aerobic allylic hydroxylation of β -pinene catalyzed by metalloporphyrins

Autor:	Yan-Ju Lu, Zhu Shouji, Yuxiang Chen, Zhen-Dong Zhao, Jing Wang, Liang-Wu Bi, Yan Gu, Xu Shichao
Rok vydání:	2017
Předmět:	Pinene Allylic rearrangement 010405 organic chemistry General Chemistry 010402 general chemistry 01 natural sciences 0104 chemical sciences Catalysis Hydroxylation Metal Solvent chemistry.chemical_compound chemistry visual_art visual_art.visual_art_medium Organic chemistry
Zdroj:	Chinese Chemical Letters. 28:575-578
ISSN:	1001-8417
DOI:	10.1016/j.cclet.2016.11.020
Popis:	Metallodeuteroporphyrins (MDPs) were employed as the catalysts for aerobic oxidation of β-pinene in absence of solvents and additives. Allylic hydroxylation products were found to be the main products from this protocol. The catalytic activity of MDPs with different metal nuclei and the influences of technological conditions on this reaction were investigated. This catalytic system has bright application prospect since only eco-friendly and readily available dioxygen were needed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e02c06fb7ec66e47abaa51780233de9b https://doi.org/10.1016/j.cclet.2016.11.020 Zobrazit plný text záznamu Full Text from ScienceDirect