Stimuli responsive amphiphilic block copolymers for aqueous media synthesised via reversible addition fragmentation chain transfer polymerisation (RAFT)

Autor:	Sébastien Garnier, Murat Mertoglu, Joachim Storsberg, Katja Skrabania, André Laschewsky
Rok vydání:	2005
Předmět:	chemistry.chemical_classification Materials science Polymers and Plastics Organic Chemistry Radical polymerization Chain transfer Raft Polymer Polyelectrolyte chemistry Chemical engineering Polymerization Amphiphile Polymer chemistry Materials Chemistry Functional polymers
Zdroj:	Polymer. 46:7726-7740
ISSN:	0032-3861
DOI:	10.1016/j.polymer.2005.03.101
Popis:	A series of RAFT agents was synthesised, and used to prepare various ionic, non-ionic and zwitterionic water-soluble polymers, in organic as well as in aqueous media. The RAFT process proved to be a powerful method to prepare functional polymers of complex structure, such as amphiphilic diblock and triblock copolymers. This includes polymers containing one or even two stimuli-sensitive hydrophilic blocks. Switching the hydrophilic character of a single or of several blocks by changing the pH, the temperature or the salt content demonstrated the variability of the molecular designs suited for stimuli-sensitive polymeric amphiphiles, and exemplified the concept of multiple-sensitive systems.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e01622ad37cb5f7257d544b0cb84d4ae https://doi.org/10.1016/j.polymer.2005.03.101 Zobrazit plný text záznamu Full Text from ScienceDirect